My 2 favorite AS splashes are Italian Barber Amici and Captains Choice Cat o Nine Tails.
Bear in mind that I only shave my head, so this may very well impact my opinion...I've never used an aftershave on my face...in fact I haven't shaved my face more than 10 times in 20 years...anyhow...
For scent, it is without a doubt the Amici. Fantastic scent, and the light menthol cooling during the dry down is simply fantastic. I crave this scent...it really is that good, and the toning and finish is quite comfortable. I never have to worry about over-toning or drying out with this one. Excellent finish, if a little mild at times, but when it feels mild, the scent still pushes it over the top, for me.
For skin feel, its the Captains Choice Co9T. This stuff hits like a ton of bricks, and the extra hot dry down just tones and firms my scalp like no other splash. WONDERFUL on especially cold days or when, as recently, I have a bad cold and I'm looking for a little extra warmth and something to clear the sinuses. I live in a very dry area, and the toning on this splash can sometimes leave my scalp feeling like an over-tightened snare drum. After dry down is complete, I sometimes use a little Nivea moisturizing gel just to help loosen that over-tight feeling. It isn't every time I use it. Just when I use it for several days in a row, or when I am experiencing an extra-dry day.